Preheat your oven to 350°F. Grease three 6-inch pans and line them with parchment paper.
Whisk the dark cocoa powder, flour, sugar, baking soda, baking powder, salt, and espresso powder.
Blend oil, egg, and sour cream together. Mix in buttermilk and vanilla.
Combine wet and dry ingredients, add hot water/coffee, and fold in chocolate chips.
Divide batter into pans. Drop on a counter to remove air bubbles. Bake for 22-25 minutes, then let them cool completely.