Preheat your oven to 350°F or 175°C. Line two 8-inch round pans with parchment paper, grease them with oil and sprinkle some flour on the sides of the pans. Set them aside.
Whisk 1 ¾ cups of flour, 2 cups of brown and granulated sugar (1 cup each), ¾ cup of cocoa powder, ¾ teaspoon of salt, and 1 ½ teaspoons of baking powder in a large bowl.
Dump in ½ cup of vegetable oil and ½ cup of melted butter. Beat them well using an electric stand or hand mixer with a paddle attachment until incorporated.
Fold in 2 large eggs, 1 egg yolk, and 2 teaspoons of vanilla extract until combined. Gradually pour in 1 cup of buttermilk and mix it until blended. Continue with the hot coffee and stir until well combined.
Pour the batter into two greased pans and bake at 350°F for 33 to 35 minutes. Let them rest in the pans for around 10 to 15 minutes. Then, free them out of the pans and allow them to cool completely on a wire rack.
Make the chocolate ganache
Microwave 1 cup of heavy whipping and 8 oz of semi-sweet chocolate on high for about 35 seconds. Whisk the mixture well and microwave for another 25 seconds. Stir until spreadable; if not, put it in the microwave for another 25 seconds. Set it aside to cool.